It was recognized from the beginning of silver gelatin emulsions that ammonia in the recipe made a faster emulsion. In 1878, D.C.E. van Monckhoven, a Belgian scientist, made an emulsion with ammonia. In 1881, Josef Maria Eder, an Austrian scientist who made incalculable contributions to photography for most of his 89 years, wrote in his book, Modern Dry Plates: Or, Emulsion Photography, p 24:
"Be the causes what they may, there is no doubt about the value of ammonia in regard to sensitiveness; and, personally, I believe that the formation of the sensitive modification of bromide of silver depends upon and varies with the solubility of the latter in ammonia."
Three years later, building on the work of Hermann Wilhelm Vogel, Eder discovered that erythrosine was an excellent green sensitizer and thereby perfected orthochromatic emulsions.
Speed and spectral sensitivity have been first order goals for most of the history of chemical photography, but especially in the beginning. If they could be delivered together in one emulsion, so much the better. Because Eder developed so many of the early formulas, and wrote prodigiously, it is no surprise that from the beginning sensitization has been done with ammoniacal emulsions. If there is an early recipe that sensitizes a plain silver emulsion, I haven't stumbled over it. But also, there aren't any reasons published that discourage the idea, so I decided I might as well give it a try. And I have been very, very pleasantly surprised.
If you have excellent ventilation in your darkroom, making converted/ammoniacal silver is no problem. But a fact about ammonia is that the stuff stinks. It really stinks in its concentrated form. With so much darkroom work being done today in make-do spaces, the odor of ammonia can be a hindrance to deeper technique. But the health and happiness of your nose isn't the only reason, or even most compelling reason to sensitize a plain silver emulsion. In this tutorial, we will be building on the AmBr Plain Silver recipe, and giving its inherent beauty added creative potential.
Slow, plain silver emulsions are beautiful. Fine grain, a full, long range of densities, and the bright, "clean" look that comes from low base fog are all the gifts of going without concentrated ammonia in the emulsion. Ammonium bromide (NH4Br, a.k.a."AmBr") as the halide in a plain silver emulsion is an almost perfect compromise between a KBr emulsion and an emulsion made in part or whole with converted silver.
Lomo Sputnik stereo camera, 2½ inch square negative.
Below left: 0.5 inch sq. crop.
Below right: 0.1 inch sq. crop.
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